Using a Vmobile phone,whats the best way to send a picture from your phone to your pc?

I really don't understand what Vmobile has got to do with the transferring of data between your phone and your PC. If your preferred mode of sending is via MMS (even though you can't send MMS messages to your PC, so it should even be out of the question here), then your service provider comes into play, but since this surely isn't the case here, then you don't need to care about your carrier.

Your phone and PC should surely have a wireless network connection established, or if your phone comes with a PC cable, then you could use that. But assuming your phone doesn't come with such an accessory, it should either have the common IrDA or Bluetooth ports.

If your 'PC' is a laptop, it should have any of the two ports for such a transfer to occur. But if it's literally a PC, then you should get an external version of either an IrDA or Bluetooth connector, provided your phone has got a similar feature.

Having all this on ground and you're on your way to sending as much files as you want from your phone to your PC. By the way, what sort of phone are you using and what sort of PC?